Molecular design, synthesis and application of photoinitiator-Catalysts (pics) for photopolymerisation reactions (Q84200)

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Project Q84200 in Poland
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English
Molecular design, synthesis and application of photoinitiator-Catalysts (pics) for photopolymerisation reactions
Project Q84200 in Poland

    Statements

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    3,868,900.0 zloty
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    928,536.0 Euro
    13 January 2020
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    3,868,900.0 zloty
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    928,536.0 Euro
    13 January 2020
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    100.0 percent
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    1 March 2018
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    28 February 2022
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    POLITECHNIKA KRAKOWSKA IM. TADEUSZA KOŚCIUSZKI
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    The main objective of the project is the design and synthesis of a new, high performance class of photoinitiators where the photoinitiator is referred to as a photoinitiator catalyst (PIC).This approach will allow creating new generation photoinitiator-catalysts which will not be used during the photopolymerization process; they will guarantee the catalytic process without the loss of efficiency during irradiation and progress of the photopolymerization; they will show perfect absorption properties adapted to modern light sources, e.g. UV-Vis-LED; importantly, they will display dual behavior through effective and efficient production in the process of initiation of the active centers such as radicals,cations or radical cations as suitable individuals initiating the photopolymerization processes; they will be dedicated to all the photopolymerization processes (cationic, free-radical, thiol-ene),as well as for controlled radical photopolymerization processes (CRP, photoATRP, PET-RAFT). (Polish)
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    The main objective of the project is the design and synthesis of a new, high performance class of photoinitiators where the photoinitiator is referred to as a photoinitiator Catalyst (PIC).This approach will allow creating new generation photoinitiator-Catalysts which will not be used during the photopolymerisation process; they will guarantee the catalytic process without the loss of efficiency during irradiation and progress of the photopolymerisation; they will show perfect absorption properties adapted to modern light sources, e.g. UV-Vis-LED; importantly, they will display dual behavior through effective and efficient production in the process of initiation of the active centers such as radicals, cations or radical cations as suitable individuals initiating the photopolymerisation processes; they will be dedicated to all the photopolymerisation processes (cationic, free-radical, thiol-ene),as well as for controlled radical photopolymerisation processes (CRP, photoATRP, PET-Raft). (English)
    14 October 2020
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    L’objectif principal du projet est la conception et la synthèse d’une nouvelle classe de photoinitiateurs de haute performance où le photoinitiateur est désigné comme un catalyseur photoinitiateur (PIC). Cette approche permettra la création de photoinitiateurs-catalyseurs de nouvelle génération qui ne seront pas utilisés pendant le processus de photopolymérisation; ils garantiront le processus catalytique sans perte d’efficacité lors de l’irradiation et de l’avancement de la photopolymérisation; ils présenteront des propriétés d’absorption parfaites adaptées aux sources lumineuses modernes, par exemple UV-Vis-LED; il est important de noter qu’ils afficheront un double comportement à travers une production efficace et efficiente dans le processus d’initiation des centres actifs tels que radicaux,cations ou cations radicaux en tant qu’individus appropriés initiant les processus de photopolymérisation; ils seront dédiés à tous les processus de photopolymérisation (cinquante, radicale libre, thiol-ène), ainsi qu’aux processus de photopolymérisation radicaux contrôlés (CRP, photoATRP, PET-RAFT). (French)
    30 November 2021
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    Das Hauptziel des Projekts ist das Design und die Synthese einer neuen, leistungsstarken Klasse von Photoinitiatoren, bei der der Photoinitiator als Photoinitiatorkatalysator (PIC) bezeichnet wird.Dieser Ansatz ermöglicht die Schaffung neuer Generation Photoinitiator-Catalysts, die während des Photopolymerisationsprozesses nicht verwendet werden; Sie garantieren den katalytischen Prozess ohne Effizienzverlust während der Bestrahlung und den Fortschritt der Photopolymerisation; Sie werden perfekte Absorptionseigenschaften aufweisen, die an moderne Lichtquellen angepasst sind, z. B. UV-Vis-LED; wichtig ist, dass sie ein doppeltes Verhalten durch effektive und effiziente Produktion im Prozess der Initiierung der aktiven Zentren wie Radikale, Kationen oder radikale Kationen als geeignete Individuen zeigen, die die Photopolymerisationsprozesse initiieren; Sie werden allen Photopolymerisationsprozessen (kationisch, freiradikale, Thiolen) sowie kontrollierten radikalen Photopolymerisationsprozessen (CRP, PhotoATRP, PET-RAFT) gewidmet. (German)
    7 December 2021
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    Het belangrijkste doel van het project is het ontwerp en de synthese van een nieuwe, hoge prestatieklasse van foto-initiators waarbij de foto-initiator wordt aangeduid als een foto-initiatorkatalysator (PIC). Deze aanpak zal het mogelijk maken nieuwe generatie foto-initiator-Catalysts te creëren die tijdens het fotopolymerisatieproces niet zullen worden gebruikt; zij garanderen het katalytisch proces zonder verlies van efficiëntie tijdens de bestraling en voortgang van de fotopolymerisatie; ze zullen perfecte absorptie-eigenschappen vertonen die zijn aangepast aan moderne lichtbronnen, bv. UV-Vis-LED; belangrijk is dat ze tweeledig gedrag zullen vertonen door effectieve en efficiënte productie in het proces van initiatie van de actieve centra zoals radicalen, kationen of radicale kationen als geschikte individuen die de Photopolymerisatieprocessen initiëren; ze zullen worden gewijd aan alle fotopolymerisatieprocessen (kationisch, vrij-radical, thiol-een), evenals aan gecontroleerde radicale fotopolymerisatieprocessen (CRP, photoATRP, PET-RAFT). (Dutch)
    16 December 2021
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    L'obiettivo principale del progetto è la progettazione e la sintesi di una nuova classe di fotoiniziatori ad alte prestazioni in cui il fotoiniziatore è indicato come un catalizzatore fotoiniziatore (PIC). Questo approccio consentirà di creare fotoiniziatori-catalisti di nuova generazione che non saranno utilizzati durante il processo di fotopolimerizzazione; garantiranno il processo catalitico senza la perdita di efficienza durante l'irradiazione e il progresso della fotopolimerizzazione; mostreranno proprietà di assorbimento perfette adattate alle sorgenti luminose moderne, ad esempio UV-Vis-LED; è importante sottolineare che essi mostreranno il duplice comportamento attraverso una produzione efficace ed efficiente nel processo di iniziazione dei centri attivi come radicali, luoghi o cationi radicali come individui adatti che avviano i processi di fotopolimerizzazione; saranno dedicati a tutti i processi di fotopolimerizzazione (cationico, free-radical, tiol-ene), nonché ai processi di fotopolimerizzazione radicali controllati (CRP, photoATRP, PET-RAFT). (Italian)
    16 January 2022
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    El objetivo principal del proyecto es el diseño y síntesis de una nueva clase de fotoiniciadores de alto rendimiento en la que el fotoiniciador se denomina catalizador fotoiniciador (PIC). Este enfoque permitirá la creación de fotoiniciadores-calalistas de nueva generación que no se utilizarán durante el proceso de fotopolimerización; garantizarán el proceso catalítico sin la pérdida de eficiencia durante la Irradiación y el progreso de la Fotopolimerización; mostrarán propiedades de absorción perfectas adaptadas a las fuentes de luz modernas, por ejemplo, UV-Vis-LED; es importante destacar que mostrarán un comportamiento dual a través de una producción eficaz y eficiente en el proceso de iniciación de los centros activos como radicales, cationes o cationes radicales como individuos adecuados que inician los procesos de fotopolimerización; se dedicarán a todos los procesos de fotopolimerización (catónicos, radicales libres, tiol-eno), así como a procesos controlados de fotopolimerización radical (CRP, photoATRP, PET-RAFT). (Spanish)
    19 January 2022
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    Identifiers

    POIR.04.04.00-00-204B/16
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