DEVELOPMENT OF NEW CATALYSTS AND TEMPLATES IN ASYMMETRIC ORGANOCATALISIS (Q3171708)
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Project Q3171708 in Spain
| Language | Label | Description | Also known as |
|---|---|---|---|
| English | DEVELOPMENT OF NEW CATALYSTS AND TEMPLATES IN ASYMMETRIC ORGANOCATALISIS |
Project Q3171708 in Spain |
Statements
148,830.0 Euro
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297,660.0 Euro
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50.0 percent
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30 December 2016
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30 April 2020
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UNIVERSIDAD DEL PAIS VASCO/EUSKAL HERRIKO UNIBERTSITATEA
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43°19'20.71"N, 1°59'2.00"W
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20069
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EL PRESENTE PROYECTO SE SUSTENTA EN RESULTADOS PREVIOS OBTENIDOS POR EL GRUPO SOLICITANTE DURANTE EL DESARROLLO DE LOS PROYECTOS DEL PN DE REFERENCIA CTQ2007-68095-C02-BQU (CATALYTIC PROCESSES FOR THE ASYMMETRIC FORMATION OF C-C AND C-X BONDS) Y CTQ2010-21263-C02 (ASYMMETRIC CATALYSIS WITH AND WITHOUT METALS: DESIGN AND APPLICATIONS), QUE EXPIRA PROXIMAMENTE._x000D_ EL OBJETIVO QUE SE PERSIGUE ES EL AVANCE DEL ESTADO DEL ARTE EN CATALISIS ASIMETRICA APLICADA A REACCIONES ORGANICAS QUE CONDUZCAN A LA FORMACION ESTEREOCONTROLADA DE ENLACES C-C Y C-X. CON TAL OBJETO SE IDENTIFICAN LOS PRINCIPALES PROBLEMAS EN EL AREA CON RESPECTO A LA REACTIVIDAD, LA ESTEROSELECTIVIDAD Y LA GENERALIDAD DE LOS METODOS ACTUALES, Y SE PROPONEN SOLUCIONES BASADAS EN LAS SIGUIENTES ESTRATEGIAS:_x000D_ (A) LA PREPARACION, CARACTERIZACION Y EVALUACION DE NUEVOS CATALIZADORES QUIRALES, CUYO DISEÑO SE BASARA EN ELEMENTOS BIOMIMETICOS, COMO SON: (I) EL CARACTER MULTIFUNCIONAL, (II) EL APROVECHAMIENTO DE INTERACCIONES REVERSIBLES MULTIPLES, EN PARTICULAR LOS "H-BOND NETWORK", (III) LAS SINERGIAS ENTRE LA CATALISIS METALICA Y LA PURAMENTE ORGANICA (CATALISIS HIBRIDA/COOPERATIVA)._x000D_ _x000D_ (B) EL DESARROLLO RACIONAL DE NUEVAS PLANTILLAS AQUIRALES QUE SEAN CAPACES DE: (I) DAR REACCIONES LIMPIAS POR ACTIVACION SELECTIVA POR DICHOS SISTEMAS CATALITICOS, (II) CONDUCIR A STEREOSELECTIVIDADES ELEVADAS, Y (III) PERMITIR UN AMPLIO ABANICO DE TRANSFORMACIONES ULTERIORES. (Spanish)
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THIS PROJECT IS BASED ON PREVIOUS RESULTS OBTAINED BY THE APPLICANT GROUP DURING THE DEVELOPMENT OF THE PROJECTS OF THE REFERENCE NP CTQ2007-68095-C02-BQU (CATALYTIC PROCESSES FOR THE ASYMMETRIC FORMATION OF C-C AND C-X BONDS) AND CTQ2010-21263-C02 (ASYMMETRIC CATALYSIS WITH AND WITHOUT METALS: Design AND APPLICATIONS), THAT EXPERIED PROXIMALY._x000D_ THE OBJECTIVE THAT IS THE ADVANCE OF THE STATE OF THE ARTEW IN Asymmetric CATALISIS APPLICATION TO ORGANIC REACTIONS leading to the STEREOCONTROL FORMATION OF C-C and C-X links. the ESTEROSELECTIVITY AND GENERALITY OF ACTUAL METHODS, AND BASED SOLUTIONS PROPOSED IN THE NEXT STRATEGYS:_x000D_ (A) PREPARATION, CHARACTERISATION AND EVALUATION OF NEW CATALISERS, WHY DESIGN TO BE based on biomimetic ELEMENTS, AS: (I) THE MULTIFUNCIONAL CHARACTER, (II) THE PROVIDED OF MULTIPLE REVERSIBLE INTERACTIONS, IN PARTICULAR THE “H-BOND NETWORK”, (III) THE SINERGIAS BETWEEN METALISIS AND THE PURAMENT ORGANIQUE (Hybrid/COOPERATIVE CATALISIS)._x000D_ _x000D__x000D_ (B) The RACIONAL DEVELOPMENT OF NEW ACHINAL PLANTILLS THAT WE CAN: (I) TO GIVE CLEAN REACTIONS BY SELECTIVE ACTIVATION BY SUCH CATALITIC SYSTEMS, (II) TO LEAD TO HIGH STEREOSELECTIVITIES, AND (III) TO ALLOW A WIDE RANGE OF SUBSEQUENT TRANSFORMATIONS. (English)
12 October 2021
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Donostia/San Sebastián
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Identifiers
CTQ2016-78487-C2-1-P
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