No label defined (Q3144477)
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Project Q3144477 in Spain
| Language | Label | Description | Also known as |
|---|---|---|---|
| English | No label defined |
Project Q3144477 in Spain |
Statements
52,030.0 Euro
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104,060.0 Euro
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50.0 percent
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1 January 2015
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31 December 2017
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UNIVERSIDAD DE VALLADOLID
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41°39'7.67"N, 4°43'42.82"W
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47186
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EL PROYECTO QUE SE PRESENTA SE DIVIDE EN DOS OBJETIVOS GENERALES. POR UN LADO SE PRETENDE PONER A PUNTO UNA SINTESIS MODULAR DE UREAS Y TIOUREAS BIFUNCIONALES, QUIRALES SOPORTADAS SOBRE DISTINTOS MATERIALES. PARA ESTE COMETIDO, SE EMPLEARAN RESINAS DE POLIESTIRENO COMERCIALES, POLIESTIRENOS DE SINTESIS, FULLERENOS Y POLIMEROS NATURALES COMO EL CHITOSAN. EN UN SEGUNDO APARTADO, SE PROPONE LA PREPARACION DE PIRROLIDINAS QUIRALES CON SUSTITUYENTES CAPACES DE COORDINAR METALES Y DE COMPORTARSE COMO CATALIZADORES BIFUNCIONALES ACTIVANDO EL NUCLEOFILO POR FORMACION DE UNA ENAMINA Y EL ELCTROFILO POR COORDINACION AL META (Spanish)
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THE PROPOSED PROJECT IS DIVIDED INTO TWO GENERAL OBJECTIVES. ON THE ONE HAND, THE AIM IS TO DEVELOP A MODULAR SYNTHESIS OF TWO-FUNCTIONAL UREAS AND THIOUREAS, CHIRALS SUPPORTED ON DIFFERENT MATERIALS. FOR THIS PURPOSE, COMMERCIAL POLYSTYRENE RESINS, SYNTHETIC POLYSTYRENE, FULLERENES AND NATURAL POLYMERS SUCH AS CHITOSAN WILL BE USED. IN A SECOND SECTION, WE PROPOSE THE PREPARATION OF CHIRAL PYRROLIDINS WITH SUBSTITUTES ABLE TO COORDINATE METALS AND BEHAVE AS BIFUNCTIONAL CATALYSTS ACTIVATING THE NUCLEOFYL BY FORMATION OF AN ENAMINE AND THE ELCTROPHY BY COORDINATION TO THE GOAL (English)
12 October 2021
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Valladolid
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Identifiers
CTQ2014-59870-P
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