Q2720791 (Q2720791): Difference between revisions
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(Created claim: summary (P836): A particularly modern research field is the development of new multi-functional materials. Among these, metal-Organic Frameworks? MOFs) have attracted great interest due to their fascinating structural characteristics and their original physical properties. In recent years, the project coordinator team has been working on the development of methods for post-synthetic modification of MOFs that include replacement through exchange reactions in MOF...) |
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A particularly modern research field is the development of new multi-functional materials. Among these, metal-Organic Frameworks? MOFs) have attracted great interest due to their fascinating structural characteristics and their original physical properties. In recent years, the project coordinator team has been working on the development of methods for post-synthetic modification of MOFs that include replacement through exchange reactions in MOFs monocrystals of either embedded or gridd solvent molecules. The objectives of this proposal include: the synthesis of new MOFs based on 3d and 4f metalloids and extended or non-multi-local substituents with polar functional groups targeting materials that combine interesting optical or magnetic or sorbent properties with the ability to modify their structures by means of reactions to their monocrystals; This project will lead to new MMOFs, swapped MMOFs with optimised properties, new synthetic methods to MMOFs, the development of original exchange reactions in MMOFs, publications in high quality international journals and announcements at leading international conferences. Finally, a high-level international team will be created consisting of the teams involved in the project, other groups from Cyprus and possibly (English) | |||||||||||||||
Property / summary: A particularly modern research field is the development of new multi-functional materials. Among these, metal-Organic Frameworks? MOFs) have attracted great interest due to their fascinating structural characteristics and their original physical properties. In recent years, the project coordinator team has been working on the development of methods for post-synthetic modification of MOFs that include replacement through exchange reactions in MOFs monocrystals of either embedded or gridd solvent molecules. The objectives of this proposal include: the synthesis of new MOFs based on 3d and 4f metalloids and extended or non-multi-local substituents with polar functional groups targeting materials that combine interesting optical or magnetic or sorbent properties with the ability to modify their structures by means of reactions to their monocrystals; This project will lead to new MMOFs, swapped MMOFs with optimised properties, new synthetic methods to MMOFs, the development of original exchange reactions in MMOFs, publications in high quality international journals and announcements at leading international conferences. Finally, a high-level international team will be created consisting of the teams involved in the project, other groups from Cyprus and possibly (English) / rank | |||||||||||||||
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Property / summary: A particularly modern research field is the development of new multi-functional materials. Among these, metal-Organic Frameworks? MOFs) have attracted great interest due to their fascinating structural characteristics and their original physical properties. In recent years, the project coordinator team has been working on the development of methods for post-synthetic modification of MOFs that include replacement through exchange reactions in MOFs monocrystals of either embedded or gridd solvent molecules. The objectives of this proposal include: the synthesis of new MOFs based on 3d and 4f metalloids and extended or non-multi-local substituents with polar functional groups targeting materials that combine interesting optical or magnetic or sorbent properties with the ability to modify their structures by means of reactions to their monocrystals; This project will lead to new MMOFs, swapped MMOFs with optimised properties, new synthetic methods to MMOFs, the development of original exchange reactions in MMOFs, publications in high quality international journals and announcements at leading international conferences. Finally, a high-level international team will be created consisting of the teams involved in the project, other groups from Cyprus and possibly (English) / qualifier | |||||||||||||||
point in time: 31 May 2021
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Revision as of 19:26, 31 May 2021
Project Q2720791 in Cyprus
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English | No label defined |
Project Q2720791 in Cyprus |
Statements
212,500.0 Euro
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250,000.0 Euro
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85.0 percent
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10 March 2017
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1 March 2022
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University of Cyprus
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Ένα ιδιαίτερα μοντέρνο ερευνητικό πεδίο είναι η ανάπτυξη νέων πολυ-λειτουργικών υλικών. Ανάμεσα σε αυτά, τα μεταλλο-οργανικά πλέγματα (Metal-Organic Frameworks ? MOFs) έχουν προσελκύσει μεγάλο ενδιαφέρον λόγω των συναρπαστικών δομικών χαρακτηριστικών τους και των πρωτότυπων φυσικών ιδιοτήτων τους. Τα τελευταία χρόνια η ομάδα του συντονιστή του έργου ασχολείται με την ανάπτυξη μεθόδων για τη μετασυνθετική τροποποίηση των MOFs που περιλαμβάνουν αντικατάσταση μέσω αντιδράσεων ανταλλαγής σε μονοκρυστάλλους των MOFs είτε ενταγμένων είτε πλεγματικών μορίων διαλύτη. Οι στόχοι της συγκεκριμένης πρότασης περιλαμβάνουν: i) τη σύνθεση νέων MOFs βασισμένων σε 3d και 4f μεταλλοϊόντα και σε εκτεταμένους ή μη πολυτοπικούς υποκαταστάτες με πολικές λειτουργικές ομάδες στοχεύοντας σε υλικά που συνδυάζουν ενδιαφέρουσες οπτικές ή μαγνητικές ή ροφητικές ιδιότητες με την ικανότητα να τροποποιούνται οι δομές τους μέσω αντιδράσεων σε μονοκρυστάλλους τους, ii) την περαιτέρω μελέτη αντιδράσεων ανταλλαγής υποκαταστατών σε μονοκρυστάλλους μέσω πραγματοποίησης σπάνιων ή ακόμη και πρωτότυπων αντιδράσεων αυτού του τύπου που οδηγούν σε ελεγχόμενη τροποποίηση των δομών νέων πολυ-λειτουργικών MOFs (multifunctional MOFs, MMOFs) και στη βελτιστοποίηση των ιδιοτήτων τους ή την απομόνωση MMOFs που οφείλουν τις ενδιαφέρουσες φυσικές ιδιότητές στους σε μόρια επισκέπτες που εισήλθαν μέσω αντιδράσεων ανταλλαγής και iii) στη λεπτομερή μελέτη των δομικών, φυσικών (μαγνητικών, φωταύγειας) και ροφητικών ιδιοτήτων των νέων και των ανταλαγμένων MOFs. Το παρόν έργο θα οδηγήσει σε νέα MMOFs, σε ανταλαγμένα MMOFs με βελτιστοποιημένες ιδιότητες, σε νέες συνθετικές μεθόδους προς MMOFs, στην ανάπτυξη πρωτότυπων αντιδράσεων ανταλλαγής σε μονοκρυστάλλους MMOFs, σε δημοσιεύσεις σε υψηλής ποιότητας διεθνή επιστημονικά περιοδικά και σε ανακοινώσεις σε κορυφαία διεθνή συνέδρια. Τέλος, θα δημιουργηθεί μία υψηλού επιπέδου διεθνής ομάδα αποτελούμενη από τις ομάδες που συμμετέχουν στο έργο, άλλες ομάδες από την Κύπρο και πιθανά (Greek)
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A particularly modern research field is the development of new multi-functional materials. Among these, metal-Organic Frameworks? MOFs) have attracted great interest due to their fascinating structural characteristics and their original physical properties. In recent years, the project coordinator team has been working on the development of methods for post-synthetic modification of MOFs that include replacement through exchange reactions in MOFs monocrystals of either embedded or gridd solvent molecules. The objectives of this proposal include: the synthesis of new MOFs based on 3d and 4f metalloids and extended or non-multi-local substituents with polar functional groups targeting materials that combine interesting optical or magnetic or sorbent properties with the ability to modify their structures by means of reactions to their monocrystals; This project will lead to new MMOFs, swapped MMOFs with optimised properties, new synthetic methods to MMOFs, the development of original exchange reactions in MMOFs, publications in high quality international journals and announcements at leading international conferences. Finally, a high-level international team will be created consisting of the teams involved in the project, other groups from Cyprus and possibly (English)
31 May 2021
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*Δεν έχει γεωγραφική διάσταση*
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Identifiers
34483
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