COVALENT HYBRIDS ON SURFACES (Q3208314): Difference between revisions
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(Created claim: summary (P836): MOLECULAR MATERIALS WILL BE KEY COMPONENTS IN FUTURE APPLICATIONS OF ELECTRONICA, MAGNETIC STORAGE, OPTOELECTRONICS AND ELECTRON PHOTON CONVERSION DEVICES SUCH AS SOLAR CELLS. CURRENTLY, MOST STUDIES THAT TAKE ADVANTAGE OF SURFACE MOLECULE INTERACTIONS FOCUS ON MOLECULAR SOLIDS STABILISED BY NON-COVALENT INTERACTIONS. THEY ARE IDEAL SYSTEMS FOR THE STUDY OF FUNDAMENTAL ASPECTS, BUT NOT FOR THE DEVELOPMENT OF APPLICATIONS. THIS COLLABORATION PROJ...) |
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| Property / budget: 6,420,408.0 Euro / rank | |||||||
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| Property / co-financing rate: 80.0 percent / rank | |||||||
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| Property / EU contribution: 5,136,326.4 Euro / rank | |||||||
Revision as of 08:54, 21 October 2021
Project Q3208314 in Spain
| Language | Label | Description | Also known as |
|---|---|---|---|
| English | COVALENT HYBRIDS ON SURFACES |
Project Q3208314 in Spain |
Statements
1 January 2014
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31 December 2016
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UNIVERSIDAD DE SANTIAGO DE COMPOSTELA
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42°52'49.51"N, 8°32'45.10"W
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15078
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LOS MATERIALES MOLECULARES SERAN COMPONENTES CLAVE EN LAS FUTURAS APLICACIONES DE LA ELECTRONICA , EL ALMACENAMIENTO MAGNETICO , LA OPTOELECTRONICA Y LOS DISPOSITIVOS DE CONVERSION DE FOTONES EN ELECTRONES COMO LAS CELULAS SOLARES. ACTUALMENTE, LA MAYORIA DE LOS ESTUDIOS QUE APROVECHAN LAS INTERACCIONES DE MOLECULAS EN SUPERFICIES SE CENTRAN EN SOLIDOS MOLECULARES ESTABILIZADOS POR INTERACCIONES NO COVALENTES. SON SISTEMAS IDEALES PARA EL ESTUDIO DE ASPECTOS FUNDAMENTALES, PERO NO PARA EL DESARROLLO DE LAS APLICACIONES. EL PRESENTE PROYECTO DE COLABORACION TIENE COMO OBJETIVO DISEÑAR NUEVAS RUTAS DE FABRICACION DE REDES MOLECULARES COVALENTES (CMNS) MEDIANTE QUIMICA EN SUPERFICIE. EL OBJETIVO ES DETECTAR, IDENTIFICAR Y CONTROLAR PROPIEDADES ELECTRONICAS Y MAGNETICAS EN ESTAS NANOESTRUCTURAS MOLECULARES. PARA HACER FRENTE A ESTE AMBICIOSO OBJETIVO ESTA COLABORACION RECOGE UN AMPLIO ESPECTRO DE TECNICAS DE FISICA DE SUPERFICIES QUE, JUNTO CON EL MODELADO TEORICO Y LA SINTESIS QUIMICA, NOS PERMITIRA OFRECER UNA IMAGEN COMPLETA DE LAS PROPIEDADES QUIMICO-FISICAS EMERGENTES QUE SE ESPERAN PARA ESTAS REDES MOLECULARES HIBRIDAS._x000D_ DENTRO DE ESTE PROYECTO FABRICAREMOS DIVERSOS CMNS A PARTIR DE PRECURSORES MOLECULARES SIMPLES, SIGUIENDO ESTRATEGIAS ASCENDENTES (DE ABAJO HACIA ARRIBA) EN SUPERFICIE . LA APROXIMACION GENERAL CONSISTIRA EN ADAPTAR LOS CONCEPTOS TRADICIONALES DE LA SINTESIS QUIMICA EN DISOLUCION AL ENTORNO BIDIMENSIONAL IMPUESTO POR LA SUPERFICIE, Y UTILIZAR EN NUESTRO BENEFICIO EL POSIBLE APORTE CATALITICO DE LA SUPERFICIE PARA AUMENTAR LA EFICIENCIA DE LA REACCION. HAY UNA GRAN VARIEDAD DE FUNCIONALIDADES MAGNETICAS, ELECTRONICAS U OPTICAS QUE SE PODRIAN CONTROLAR MEDIANTE EL DISEÑO DE LOS PRECURSORES MOLECULARES. POR ESTA RAZON, EL GRUPO DE QUIMICA SINTETICA DE LA USC DESEMPEÑA UN PAPEL FUNDAMENTAL EN EL DISEÑO Y EN LA SINTESIS DE LOS PRECURSORES ORGANICOS. VAMOS A APROVECHAR PARA ELLO NUESTRA AMPLIA EXPERIENCIA EN CATALISIS HOMOGENEA METALICA EN DISOLUCION Y EN LA PREPARACION DE GRANDES MOLECULAS AROMATICAS Y NANOGRAFENOS CON DIFERENTES TOPOLOGIAS Y PERIFERIAS. EN PRIMER LUGAR, NOS CENTRAREMOS EN EL DISEÑO Y SINTESIS DE PRECURSORES AROMATICOS PARA LA CONSTRUCCION DE NANOESTRUCTURAS DE GRAFENO MEDIANTE ACOPLAMIENTOS ULLMANN, DE MANERA QUE CONSIGAMOS UN CONTROL COMPLETO DE LA ESTRUCTURA ATOMICA FINAL DEL MATERIAL, INCLUIDO SU TAMAÑO Y SU FORMA. PERO TAMBIEN VAMOS A CONTRIBUIR A EXPLORAR NUEVAS REACCIONES DE ACOPLAMIENTO Y RUTAS SINTETICAS QUE PODRIAN PROPORCIONAR HERRAMIENTAS ADICIONALES PARA LOGRAR LA CONSTRUCCION JERARQUICA DE DIVERSAS CMNS EN DIFERENTES SUPERFICIES. ESTE CONOCIMIENTO ADQUIRIDO SE UTILIZARA EN LA SINTESIS DE MONOMEROS Y PRECURSORES CLAVE CON ESTRUCTURA Y FUNCIONALIZACION ADECUADA PARA LA PREPARACION DE OTROS CMNS COMO LAS NANOESTRUCTURAS DE NITRURO DE BORO HEXAGONAL (HBN), LOS HIBRIDOS BN-C, LAS REDES MOLECULARES DADOR-ACEPTOR, LAS NANOESTRUCTURAS COVALENTES METALORGANICAS, LAS NANOCINTAS DE GRAFENO DOPADAS CON NITROGENO O LAS REDES MOLECULARES BASADAS EN NUCLEOS DE FENACENOS._x000D_ EN RESUMEN , TENEMOS LA INTENCION DE DISEÑAR, CONSTRUIR Y CARACTERIZAR ESTRUCTURAS MOLECULARES COVALENTES FUNCIONALES CON POTENCIAL APLICACION EN ELECTRONICA, OPTICA Y MAGNETISMO. ESTO SOLO SE PODRA LOGRAR MEDIANTE EL TRABAJO COLABORATIVO DE GRUPOS CON EXPERIENCIA EN LA QUIMICA ORGANICA, LA CIENCIA DE SUPERFICIES, LA ESPECTRO- MICROSCOPIA DE SONDA DE BARRIDO Y LAS SIMULACIONES TEORICAS. (Spanish)
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MOLECULAR MATERIALS WILL BE KEY COMPONENTS IN FUTURE APPLICATIONS OF ELECTRONICA, MAGNETIC STORAGE, OPTOELECTRONICS AND ELECTRON PHOTON CONVERSION DEVICES SUCH AS SOLAR CELLS. CURRENTLY, MOST STUDIES THAT TAKE ADVANTAGE OF SURFACE MOLECULE INTERACTIONS FOCUS ON MOLECULAR SOLIDS STABILISED BY NON-COVALENT INTERACTIONS. THEY ARE IDEAL SYSTEMS FOR THE STUDY OF FUNDAMENTAL ASPECTS, BUT NOT FOR THE DEVELOPMENT OF APPLICATIONS. THIS COLLABORATION PROJECT AIMS TO DESIGN NEW MANUFACTURING ROUTES OF COVALENT MOLECULAR NETWORKS (CMNS) USING SURFACE CHEMISTRY. THE OBJECTIVE IS TO DETECT, IDENTIFY AND CONTROL ELECTRONIC AND MAGNETIC PROPERTIES IN THESE MOLECULAR NANOSTRUCTURES. To FRANCE TO THIS AMBICIOUS OBJECTIVE THIS COLABORATION RECEIVES A SPECTER OF SUPERFICIES TECHNICAL TECHNICAL TECHNICAL TECHNICAL TECHNICAL TECHNOLOGY WITH THE THEORIC MODEL AND SINTESIS CHEMICAL, we will allow us to offer a complete picture of the EMERGENCY CHMICO-FISICAS PROPERTYS that are expected for these HIBRID MOLECULAR NETWORKS._x000D_ DENTRO DE THIS PROJECT we will manufacture CMNS DIVERSOS TO PART OF SIMPLES MOLECULAR PRECURSORES, Following ascending STRATEGYS (Of DOWN HACIA ARRIBA) IN SUPERFICE. THE GENERAL APPROACH WILL CONSIST OF ADAPTING THE TRADITIONAL CONCEPTS OF THE CHEMICAL SYNTHESIS IN SOLUTION TO THE TWO-DIMENSIONAL ENVIRONMENT IMPOSED BY THE SURFACE, AND TO USE FOR OUR BENEFIT THE POSSIBLE CATALITIC CONTRIBUTION OF THE SURFACE TO INCREASE THE EFFICIENCY OF THE REACTION. THERE ARE A VARIETY OF MAGNETIC, ELECTRONIC OR OPTICAL FUNCTIONALITIES THAT COULD BE CONTROLLED BY THE DESIGN OF MOLECULAR PRECURSORS. FOR THIS REASON, THE USC SYNTHETIC CHEMISTRY GROUP PLAYS A FUNDAMENTAL ROLE IN THE DESIGN AND SYNTHESIS OF ORGANIC PRECURSORS. FOR THIS WE WILL TAKE ADVANTAGE OF OUR EXTENSIVE EXPERIENCE IN CATALYSIS HOMOGENEOUS METAL IN SOLUTION AND IN THE PREPARATION OF LARGE AROMATIC MOLECULES AND NANOGRAPHENOS WITH DIFFERENT TOPOLOGIAS AND PERIPHERIES. FIRST, WE WILL FOCUS ON THE DESIGN AND SYNTHESIS OF AROMATIC PRECURSORS FOR THE CONSTRUCTION OF GRAPHENE NANOSTRUCTURES THROUGH ULLMANN COUPLINGS, SO THAT WE GET COMPLETE CONTROL OF THE FINAL ATOMIC STRUCTURE OF THE MATERIAL, INCLUDING ITS SIZE AND SHAPE. BUT WE WILL ALSO CONTRIBUTE TO EXPLORING NEW COUPLING REACTIONS AND SYNTHETIC ROUTES THAT COULD PROVIDE ADDITIONAL TOOLS TO ACHIEVE THE HIERARCHICAL CONSTRUCTION OF VARIOUS CMNS ON DIFFERENT SURFACES. This ADQUIRIED KNOWING shall be used in the synthesis of monomers and key-prisoners with STRUCTURE AND FUNCIONALISATION ADECTED FOR THE PREPARATION OF OTHER CMNS as HEXAGONAL BORO Nitride Nanostrecturings (HBN), the BN-C HIBRIDS, DADOR-acceptor MOLECULARY NETWORKS, METALORGANIC COvalent NANOSTRUCTURES, GRAFENO-doped nano-tapes or NITROGENO-doped MULLEAL NIGHTS or MULLECULARY NETWORKS BN-C, we HAVE THE INTENCTION OF DESIGNING, CONSTRUCTURES AND Characterising FUNCIONAL MOLECULAR STRUCTURES WITH POTENTIAL APPLICATION IN ELECTRONIC, OPTICAL AND MAGNETISM. THIS CAN ONLY BE ACHIEVED THROUGH THE COLLABORATIVE WORK OF GROUPS WITH EXPERIENCE IN ORGANIC CHEMISTRY, SURFACE SCIENCE, SCANNING PROBE MICROSCOPY AND THEORETICAL SIMULATIONS. (English)
13 October 2021
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Santiago de Compostela
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Identifiers
MAT2013-46593-C6-6-P
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