CATALYST AND REACTOR INNOVATIONS TO ENHANCE CO2 CAPTURE IN DIMETHYL ETHER SYNTHESIS (DME) (Q3165383): Difference between revisions

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(‎Changed label, description and/or aliases in en: translated_label)
(‎Removed claim: summary (P836): TWO INNOVATIONS (IN THE CONFIGURATION OF THE REACTOR AND IN THE PREPARATION OF THE BIFUNCTIONAL CATALYST) WILL BE STUDIED IN THE PROCESS OF SYNTHESIS OF DIMETHYL ETHER (DME) IN A STAGE IN GAS PHASE, (STD PROCESS), TO PROMOTE THE CONVERSION OF CO2-FUELED WITH THE SYNTHESIS GAS. THE PURPOSE OF THE TWO INNOVATIONS IS TO SEPARATE THE H2O FROM THE REACTION MEDIUM TO FAVOR THE KEY REACTIONS FOR THE CONVERSION OF CO2 (METHANOL SYNTHESIS AND WGS) LIMI...)
Property / summary
TWO INNOVATIONS (IN THE CONFIGURATION OF THE REACTOR AND IN THE PREPARATION OF THE BIFUNCTIONAL CATALYST) WILL BE STUDIED IN THE PROCESS OF SYNTHESIS OF DIMETHYL ETHER (DME) IN A STAGE IN GAS PHASE, (STD PROCESS), TO PROMOTE THE CONVERSION OF CO2-FUELED WITH THE SYNTHESIS GAS. THE PURPOSE OF THE TWO INNOVATIONS IS TO SEPARATE THE H2O FROM THE REACTION MEDIUM TO FAVOR THE KEY REACTIONS FOR THE CONVERSION OF CO2 (METHANOL SYNTHESIS AND WGS) LIMITED THERMODYNAMICALLY AND CINEMATICALLY BY THE CONCENTRATION OF H2O AND ALSO FAVORING DEHYDRATION OF METHANOL. THE AUTHORS HAVE EXTENSIVE EXPERIENCE IN DIFFERENT FACETS OF THE STD PROCESS (COMPOSITION OF THE BIFUNCTIONAL CATALYST, CINETICO MODELING) AND WITH THE NECESSARY EQUIPMENT, WHICH WILL ADAPT FOR THE INCORPORATION OF THE REACTOR/MEMBRANE SYSTEM. _x000D_ the NEW REACTION SYSTEM will be a fix-reader with a hydrophilic MEMBRANE AS EXTERNAL PARE AND chromatographic COMPONENT SYSTEM (DME, METANOL, CO2, CO, H2, H2, H2, H2O) of the REACTOR’s and MEMBRANA CORRIENTS. THE CATALYST PARTICLES WILL BE MADE UP OF TWO NEW STRUCTURES: I) DOES SHELL, BY ENCAPSULATING THE METAL FUNCTION (CUO-ZNO-MNO) WITH THE ACID FUNCTION (TOAD-18), WHOSE FUNCTION IS MEMBRANE, TO FACILITATE THE TRANSFER OF H2O AWAY FROM THE METAL FUNCTION; CAPTURE OF CO2 BY AGGLOMERATION WITH BOEMITE (AS H2O ADSORBENT) FROM THE MIXTURE OF THE METALLIC AND ACID FUNCTIONS. AFTER THE DISCRIMINATION OF CATALYSTS, WITH THE SELECTED ONE (ACCORDING TO THE COMMITMENT (PERFORMANCE OF DME)-(CONVERSION OF CO2)- STABILITY, THE CAUSES AND MECHANISM OF THE DEACTIVATION OF THE CATALYST BY COKE FORMATION (KEY ASPECT FOR THE VIABILITY OF THE PROCESS) WILL BE STUDIED AND THE CINETICO MODELING CARRIED OUT IN ORDER TO QUANTIFY THE EFFECT OF THE CONDITIONS (CONCENTRATION OF THE COMPONENTS OF THE REACTION MEDIUM AND TEMPERATURE) ON THE DISTRIBUTION OF THE PRODUCT AND ITS EVOLUTION OVER TIME. _x000D_ the TECHNOLOGY OF THE (Second Reading REACTOR)/MEMBRANA BEING STUDIATED MEDIATING SIMULACION (UTILISING THE Cinematic MODEL FOR A CONVENTIONAL CATALISER OF CUO-ZNO-MNO/SAPO-18) AND WITH an EXPERIMENTAL INSTALLATION (Constructed to the PROJECT COMMITTEE), WITH ALTERNATIVE STRATEGIC DIFFERENTS OF BARRIDO IN MEMBER. THE EXPERIMENTAL STUDY WILL VALIDATE THE SIMULATION AND BOTH WILL BE PERFORMED IN THE SAME INTERVAL OF CONDITIONS AS THE PREVIOUS CINETICO MODELING: PRESSURE (20-50 ATM), TEMPERATURE (200-325 °C); SPACE TIME (0.1-70 GCAT H/(MOL COX); Relationship H2/COX IN FOOD (2-4), CO2/COX RELATION (0-1), TIME (HASTA 30 H)._x000D_ OPTIMAL OPERATION CONDITIONS (COMO ALTERNATIVAS: MAXIMUM PERFORMANCE OF DME OR CO2 CONVERSION OR A COMMITMENT OF BOTH), COMPARING THE PERFORMANCE OF THE TECHNOLOGY DEVELOPED INTEGRATING THE TWO INNOVATIONS, WITH RESPECT TO THE OPTIMAL CONDITIONS INCORPORATING INTO THE CONVENTIONAL STD PROCESS EACH INITIATIVE SEPARATELY, AS WELL AS THE LIMITATIONS AND PROSPECTS OF SCALE-UP FOR THE INDUSTRIAL IMPLEMENTATION OF THE PROPOSED TECHNOLOGY. (English)
 
Property / summary: TWO INNOVATIONS (IN THE CONFIGURATION OF THE REACTOR AND IN THE PREPARATION OF THE BIFUNCTIONAL CATALYST) WILL BE STUDIED IN THE PROCESS OF SYNTHESIS OF DIMETHYL ETHER (DME) IN A STAGE IN GAS PHASE, (STD PROCESS), TO PROMOTE THE CONVERSION OF CO2-FUELED WITH THE SYNTHESIS GAS. THE PURPOSE OF THE TWO INNOVATIONS IS TO SEPARATE THE H2O FROM THE REACTION MEDIUM TO FAVOR THE KEY REACTIONS FOR THE CONVERSION OF CO2 (METHANOL SYNTHESIS AND WGS) LIMITED THERMODYNAMICALLY AND CINEMATICALLY BY THE CONCENTRATION OF H2O AND ALSO FAVORING DEHYDRATION OF METHANOL. THE AUTHORS HAVE EXTENSIVE EXPERIENCE IN DIFFERENT FACETS OF THE STD PROCESS (COMPOSITION OF THE BIFUNCTIONAL CATALYST, CINETICO MODELING) AND WITH THE NECESSARY EQUIPMENT, WHICH WILL ADAPT FOR THE INCORPORATION OF THE REACTOR/MEMBRANE SYSTEM. _x000D_ the NEW REACTION SYSTEM will be a fix-reader with a hydrophilic MEMBRANE AS EXTERNAL PARE AND chromatographic COMPONENT SYSTEM (DME, METANOL, CO2, CO, H2, H2, H2, H2O) of the REACTOR’s and MEMBRANA CORRIENTS. THE CATALYST PARTICLES WILL BE MADE UP OF TWO NEW STRUCTURES: I) DOES SHELL, BY ENCAPSULATING THE METAL FUNCTION (CUO-ZNO-MNO) WITH THE ACID FUNCTION (TOAD-18), WHOSE FUNCTION IS MEMBRANE, TO FACILITATE THE TRANSFER OF H2O AWAY FROM THE METAL FUNCTION; CAPTURE OF CO2 BY AGGLOMERATION WITH BOEMITE (AS H2O ADSORBENT) FROM THE MIXTURE OF THE METALLIC AND ACID FUNCTIONS. AFTER THE DISCRIMINATION OF CATALYSTS, WITH THE SELECTED ONE (ACCORDING TO THE COMMITMENT (PERFORMANCE OF DME)-(CONVERSION OF CO2)- STABILITY, THE CAUSES AND MECHANISM OF THE DEACTIVATION OF THE CATALYST BY COKE FORMATION (KEY ASPECT FOR THE VIABILITY OF THE PROCESS) WILL BE STUDIED AND THE CINETICO MODELING CARRIED OUT IN ORDER TO QUANTIFY THE EFFECT OF THE CONDITIONS (CONCENTRATION OF THE COMPONENTS OF THE REACTION MEDIUM AND TEMPERATURE) ON THE DISTRIBUTION OF THE PRODUCT AND ITS EVOLUTION OVER TIME. _x000D_ the TECHNOLOGY OF THE (Second Reading REACTOR)/MEMBRANA BEING STUDIATED MEDIATING SIMULACION (UTILISING THE Cinematic MODEL FOR A CONVENTIONAL CATALISER OF CUO-ZNO-MNO/SAPO-18) AND WITH an EXPERIMENTAL INSTALLATION (Constructed to the PROJECT COMMITTEE), WITH ALTERNATIVE STRATEGIC DIFFERENTS OF BARRIDO IN MEMBER. THE EXPERIMENTAL STUDY WILL VALIDATE THE SIMULATION AND BOTH WILL BE PERFORMED IN THE SAME INTERVAL OF CONDITIONS AS THE PREVIOUS CINETICO MODELING: PRESSURE (20-50 ATM), TEMPERATURE (200-325 °C); SPACE TIME (0.1-70 GCAT H/(MOL COX); Relationship H2/COX IN FOOD (2-4), CO2/COX RELATION (0-1), TIME (HASTA 30 H)._x000D_ OPTIMAL OPERATION CONDITIONS (COMO ALTERNATIVAS: MAXIMUM PERFORMANCE OF DME OR CO2 CONVERSION OR A COMMITMENT OF BOTH), COMPARING THE PERFORMANCE OF THE TECHNOLOGY DEVELOPED INTEGRATING THE TWO INNOVATIONS, WITH RESPECT TO THE OPTIMAL CONDITIONS INCORPORATING INTO THE CONVENTIONAL STD PROCESS EACH INITIATIVE SEPARATELY, AS WELL AS THE LIMITATIONS AND PROSPECTS OF SCALE-UP FOR THE INDUSTRIAL IMPLEMENTATION OF THE PROPOSED TECHNOLOGY. (English) / rank
Normal rank
 
Property / summary: TWO INNOVATIONS (IN THE CONFIGURATION OF THE REACTOR AND IN THE PREPARATION OF THE BIFUNCTIONAL CATALYST) WILL BE STUDIED IN THE PROCESS OF SYNTHESIS OF DIMETHYL ETHER (DME) IN A STAGE IN GAS PHASE, (STD PROCESS), TO PROMOTE THE CONVERSION OF CO2-FUELED WITH THE SYNTHESIS GAS. THE PURPOSE OF THE TWO INNOVATIONS IS TO SEPARATE THE H2O FROM THE REACTION MEDIUM TO FAVOR THE KEY REACTIONS FOR THE CONVERSION OF CO2 (METHANOL SYNTHESIS AND WGS) LIMITED THERMODYNAMICALLY AND CINEMATICALLY BY THE CONCENTRATION OF H2O AND ALSO FAVORING DEHYDRATION OF METHANOL. THE AUTHORS HAVE EXTENSIVE EXPERIENCE IN DIFFERENT FACETS OF THE STD PROCESS (COMPOSITION OF THE BIFUNCTIONAL CATALYST, CINETICO MODELING) AND WITH THE NECESSARY EQUIPMENT, WHICH WILL ADAPT FOR THE INCORPORATION OF THE REACTOR/MEMBRANE SYSTEM. _x000D_ the NEW REACTION SYSTEM will be a fix-reader with a hydrophilic MEMBRANE AS EXTERNAL PARE AND chromatographic COMPONENT SYSTEM (DME, METANOL, CO2, CO, H2, H2, H2, H2O) of the REACTOR’s and MEMBRANA CORRIENTS. THE CATALYST PARTICLES WILL BE MADE UP OF TWO NEW STRUCTURES: I) DOES SHELL, BY ENCAPSULATING THE METAL FUNCTION (CUO-ZNO-MNO) WITH THE ACID FUNCTION (TOAD-18), WHOSE FUNCTION IS MEMBRANE, TO FACILITATE THE TRANSFER OF H2O AWAY FROM THE METAL FUNCTION; CAPTURE OF CO2 BY AGGLOMERATION WITH BOEMITE (AS H2O ADSORBENT) FROM THE MIXTURE OF THE METALLIC AND ACID FUNCTIONS. AFTER THE DISCRIMINATION OF CATALYSTS, WITH THE SELECTED ONE (ACCORDING TO THE COMMITMENT (PERFORMANCE OF DME)-(CONVERSION OF CO2)- STABILITY, THE CAUSES AND MECHANISM OF THE DEACTIVATION OF THE CATALYST BY COKE FORMATION (KEY ASPECT FOR THE VIABILITY OF THE PROCESS) WILL BE STUDIED AND THE CINETICO MODELING CARRIED OUT IN ORDER TO QUANTIFY THE EFFECT OF THE CONDITIONS (CONCENTRATION OF THE COMPONENTS OF THE REACTION MEDIUM AND TEMPERATURE) ON THE DISTRIBUTION OF THE PRODUCT AND ITS EVOLUTION OVER TIME. _x000D_ the TECHNOLOGY OF THE (Second Reading REACTOR)/MEMBRANA BEING STUDIATED MEDIATING SIMULACION (UTILISING THE Cinematic MODEL FOR A CONVENTIONAL CATALISER OF CUO-ZNO-MNO/SAPO-18) AND WITH an EXPERIMENTAL INSTALLATION (Constructed to the PROJECT COMMITTEE), WITH ALTERNATIVE STRATEGIC DIFFERENTS OF BARRIDO IN MEMBER. THE EXPERIMENTAL STUDY WILL VALIDATE THE SIMULATION AND BOTH WILL BE PERFORMED IN THE SAME INTERVAL OF CONDITIONS AS THE PREVIOUS CINETICO MODELING: PRESSURE (20-50 ATM), TEMPERATURE (200-325 °C); SPACE TIME (0.1-70 GCAT H/(MOL COX); Relationship H2/COX IN FOOD (2-4), CO2/COX RELATION (0-1), TIME (HASTA 30 H)._x000D_ OPTIMAL OPERATION CONDITIONS (COMO ALTERNATIVAS: MAXIMUM PERFORMANCE OF DME OR CO2 CONVERSION OR A COMMITMENT OF BOTH), COMPARING THE PERFORMANCE OF THE TECHNOLOGY DEVELOPED INTEGRATING THE TWO INNOVATIONS, WITH RESPECT TO THE OPTIMAL CONDITIONS INCORPORATING INTO THE CONVENTIONAL STD PROCESS EACH INITIATIVE SEPARATELY, AS WELL AS THE LIMITATIONS AND PROSPECTS OF SCALE-UP FOR THE INDUSTRIAL IMPLEMENTATION OF THE PROPOSED TECHNOLOGY. (English) / qualifier
point in time: 12 October 2021
Timestamp+2021-10-12T00:00:00Z
Timezone+00:00
CalendarGregorian
Precision1 day
Before0
After0
 

Revision as of 16:58, 12 October 2021

Project Q3165383 in Spain
Language Label Description Also known as
English
CATALYST AND REACTOR INNOVATIONS TO ENHANCE CO2 CAPTURE IN DIMETHYL ETHER SYNTHESIS (DME)
Project Q3165383 in Spain

    Statements

    contained in NUTS
    Biscay
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    country
    Spain
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    EU contribution
    145,200.0 Euro
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    budget
    290,400.0 Euro
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    co-financing rate
    50.0 percent
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    start time
    1 January 2014
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    end time
    30 June 2017
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    beneficiary name (string)
    UNIVERSIDAD DEL PAIS VASCO/EUSKAL HERRIKO UNIBERTSITATEA
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    beneficiary
    Q3134714
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    coordinate location

    43°19'37.56"N, 2°59'4.60"W
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    postal code
    48054
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    summary
    SE ESTUDIARAN DOS INNOVACIONES (EN LA CONFIGURACION DEL REACTOR Y EN LA PREPARACION DEL CATALIZADOR BIFUNCIONAL) EN EL PROCESO DE SINTESIS DE DIMETIL ETER (DME) EN UNA ETAPA EN FASE GAS, (PROCESO STD), PARA FAVORECER LA CONVERSION DEL CO2 CO-ALIMENTADO CON EL GAS DE SINTESIS. LA FINALIDAD DE LAS DOS INNOVACIONES ES SEPARAR EL H2O DEL MEDIO DE REACCION PARA FAVORECER LAS REACCIONES CLAVE PARA LA CONVERSION DEL CO2 (SINTESIS DE METANOL Y WGS) LIMITADAS TERMODINAMICA Y CINETICAMENTE POR LA CONCENTRACION DE H2O Y FAVORECIENDO ADEMAS LA DESHIDRATACION EL METANOL. LOS AUTORES CUENTAN CON UNA AMPLIA EXPERIENCIA EN DIFERENTES FACETAS DEL PROCESO STD (COMPOSICION DEL CATALIZADOR BIFUNCIONAL, MODELADO CINETICO) Y CON EL EQUIPAMIENTO NECESARIO, QUE ADECUARAN PARA LA INCORPORACION DEL SISTEMA REACTOR/MEMBRANA. _x000D_ EL NUEVO SISTEMA DE REACCION SERA UN REACTOR DE LECHO FIJO CON UNA MEMBRANA HIDROFILICA COMO PARED EXTERNA Y CON SEGUIMIENTO CROMATOGRAFICO DE LOS COMPONENTES (DME, METANOL, CO2, CO, H2, HIDROCARBUROS Y H2O) DE LAS CORRIENTES DEL REACTOR Y DE LA MEMBRANA. LAS PARTICULAS DE CATALIZADOR SERAN CONFORMADAS CON DOS NUEVAS ESTRUCTURAS: I) ¿CORE SHELL¿, MEDIANTE ENCAPSULAMIENTO DE LA FUNCION METALICA (CUO-ZNO-MNO) CON LA FUNCION ACIDA (SAPO-18), CUYA FUNCION ES LA DE MEMBRANA, PARA FACILITAR LA TRANSFERENCIA DEL H2O ALEJANDOLA DE LA FUNCION METALICA; II) ¿CAPTURA DE CO2¿ MEDIANTE LA AGLOMERACION CON BOEMITA (COMO ADSORBENTE DE H2O) DE LA MEZCLA DE LAS FUNCIONES METALICA Y ACIDA. TRAS LA DISCRIMINACION DE CATALIZADORES, CON EL SELECCIONADO (ATENDIENDO AL COMPROMISO (RENDIMIENTO DE DME)-(CONVERSION DE CO2)- ESTABILIDAD, SE ESTUDIARAN LAS CAUSAS Y MECANISMO DE LA DESACTIVACION DEL CATALIZADOR POR FORMACION DE COQUE (ASPECTO CLAVE PARA LA VIABILIDAD DEL PROCESO) Y SE REALIZARA EL MODELADO CINETICO CON OBJETO DE CUANTIFICAR EL EFECTO DE LAS CONDICIONES (CONCENTRACION DE LOS COMPONENTES DEL MEDIO DE REACCION Y TEMPERATURA) SOBRE LA DISTRIBUCION DE PRODUCTO Y SU EVOLUCION CON EL TIEMPO. _x000D_ LA TECNOLOGIA DEL (REACTOR DE LECHO FIJO)/MEMBRANA SERA ESTUDIADA MEDIANTE SIMULACION (UTILIZANDO EL MODELO CINETICO PARA UN CATALIZADOR CONVENCIONAL DE CUO-ZNO-MNO/SAPO-18) Y CON UNA INSTALACION EXPERIMENTAL (CONSTRUIDA AL COMIENZO DEL PROYECTO), CON DIFERENTES ESTRATEGIAS ALTERNATIVAS DE BARRIDO EN LA MEMBRANA. EL ESTUDIO EXPERIMENTAL VALIDARA AL DE SIMULACION Y AMBOS SE REALIZARAN EN EL MISMO INTERVALO DE CONDICIONES QUE EL MODELADO CINETICO PREVIO: PRESION (20-50 ATM), TEMPERATURA (200-325 ºC); TIEMPO ESPACIAL (0.1-70 GCAT H/(MOL COX); RELACION H2/ COX EN LA ALIMENTACION (2-4), RELACION CO2/COX (0-1), TIEMPO (HASTA 30 H)._x000D_ SE ESTABLECERAN LAS CONDICIONES OPTIMAS DE OPERACION (COMO ALTERNATIVAS: MAXIMO RENDIMIENTO DE DME O DE CONVERSION DE CO2 O UN COMPROMISO DE AMBOS), COMPARANDO LAS PRESTACIONES DE LA TECNOLOGIA DESARROLLADA INTEGRANDO LAS DOS INNOVACIONES, CON RESPECTO A LAS CONDICIONES OPTIMAS INCORPORANDO EN EL PROCESO STD CONVENCIONAL CADA INICIATIVA POR SEPARADO, ASI COMO LAS LIMITACIONES Y PERSPECTIVAS DE AUMENTO DE ESCALA PARA LA IMPLANTACION INDUSTRIAL DE LA TECNOLOGIA PROPUESTA. (Spanish)
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    location (string)
    Leioa
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    Identifiers

    Spanish Kohesio ID
    CTQ2013-46173-R
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