POROUS COORDINATION POLYMERS AS CHEMICAL REACTORS FOR NEW ADVANCED MATERIALS: CHEMISTRY IN CONFINED SPACES (Q3136013): Difference between revisions
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(Created claim: summary (P836): THIS PROPOSAL AIMS TO TAKE A STEP FURTHER IN THE USE OF A TYPE OF POROUS MATERIALS, CALLED METAL-ORGANIC FRAMEWORKS (MOFS), AS NANO-REACTORS FOR THE DESIGN OF NEW ADVANCED MATERIALS WITH TECHNOLOGICAL APPLICATIONS AS WELL AS FOR THE STUDY OF BIOLOGICAL PROCESSES OF FUNDAMENTAL INTEREST IN LIFE SCIENCES. TO THIS END, WE HAVE DESIGNED A NOVEL SYNTHETIC STRATEGY CONSISTING OF A PRIOR RATIONAL DESIGN OF MOFS WITH FUNCTIONAL CHANNELS (IN SIZE, SHAPE...) |
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POROUS COORDINATION POLYMERS AS CHEMICAL REACTORS FOR NEW ADVANCED MATERIALS: CHEMISTRY IN CONFINED SPACES | |||
Revision as of 13:14, 12 October 2021
Project Q3136013 in Spain
| Language | Label | Description | Also known as |
|---|---|---|---|
| English | POROUS COORDINATION POLYMERS AS CHEMICAL REACTORS FOR NEW ADVANCED MATERIALS: CHEMISTRY IN CONFINED SPACES |
Project Q3136013 in Spain |
Statements
34,485.0 Euro
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68,970.0 Euro
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50.0 percent
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30 December 2016
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31 December 2020
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UNIVERSIDAD DE VALENCIA
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39°30'14.11"N, 0°26'31.56"W
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46190
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LA PRESENTE PROPUESTA PRETENDE DAR UN PASO MAS ALLA EN EL USO DE UN TIPO DE MATERIALES POROSOS, LLAMADOS METAL-ORGANIC FRAMEWORKS (MOFS), COMO NANO-REACTORES PARA EL DISEÑO DE NUEVOS MATERIALES AVANZADOS CON APLICACIONES TECNOLOGICAS ASI COMO PARA EL ESTUDIO DE PROCESOS BIOLOGICOS DE INTERES FUNDAMENTAL EN CIENCIAS DE LA VIDA. CON ESTE FIN, HEMOS DISEÑADO UNA ESTRATEGIA SINTETICA NOVEDOSA CONSISTENTE EN UN DISEÑO RACIONAL PREVIO DE MOFS CON CANALES FUNCIONALES (EN TAMAÑO, FORMA Y REACTIVIDAD) Y LA APLICACION POSTERIOR DE LOS LLAMADOS METODOS POST-SINTETICOS. DE ESTE MODO, SE SINTETIZARAN NUEVAS ESPECIES FUNCIONALES, MEDIANTE UN PROCESO DE RECONOCIMIENTO MOLECULAR, EN EL INTERIOR DE LOS POROS DE LOS MOFS, CUYAS PROPIEDADES FISICAS Y QUIMICAS SERAN MODULADAS POR LAS PROPIEDADES DE DICHOS POROS._x000D_ EL USO DE MOFS, LOS CUALES POSEEN CARACTER POROSO Y UNA RICA QUIMICA "HUESPED-ANFITRION", COMO "REACTORES QUIMICOS" HA EMERGIDO RECIENTEMENTE COMO UNA DE LAS VIAS MAS PROMETEDORAS PARA EL DISEÑO DE NUEVOS MATERIALES FUNCIONALES. SIN EMBARGO, ESTA ESTRATEGIA TODAVIA PRESENTA SERIAS CARENCIAS EN CUANTO AL CONTROL DE LA ESTRUCTURA DE LA ESPECIE FINAL, SU CARACTERIZACION ESTRUCTURAL Y EL CONTROL DE LAS PROPIEDADES DE LA ESPECIE RESULTANTE._x000D_ EL PRESENTE PROYECTO SE SITUA EN EL CENTRO DE LAS MENCIONADAS DEFICIENCIAS. POR ELLO, CON LA PROMETEDORA PERSPECTIVA DE NUESTROS RESULTADOS PRELIMINARES (VER APARTADO C), NUESTRA ESTRATEGIA SE BASA EN UN DISEÑO PREVIO DE UNA LARGA BATERIA DE MOFS DE POROSIDADES CONTROLADAS EN TERMINOS DE TAMAÑO, FORMA Y FUNCIONALIDAD. A CONTINUACION, SE SINTETIZARAN QUIMICAMENTE NUEVAS ESPECIES FUNCIONALES EN EL INTERIOR DE DICHOS POROS APROVECHANDONOS DEL EFECTO PLANTILLA DE LOS MISMOS ASI COMO DE SUS PROPIEDADES. ADEMAS, PRETENDEMOS UTILIZAR LA CRISTALOGRAFIA COMO HERRAMIENTA PODEROSA PARA APORTAR LUZ SOBRE LAS ESTRUCTURAS DE LAS ESPECIES CREADAS, YENDO UN PASO MAS ALLA DE TODO LO HECHO HASTA LA FECHA._x000D_ TENIENDO EN CUENTA TODO LO MENCIONADO, SE SINTETIZARAN NUEVOS MATERIALES AVANZADOS CON DIVERSAS Y NOVEDOSAS PROPIEDADES QUIMICAS (CATALISIS, BIOMIMETICAS, ETC) Y FISICAS (OPTICAS, ELECTRICAS, MAGNETICAS, CONDUCTORAS, ETC). ESTOS NUEVOS MATERIALES PRETENDEN TENER APLICACION EN EL CAMPO DE LOS MULTIFERROICOS (Y MATERIALES DE OPTICA NO LINEAL), LOS CUALES SON DE FUNDAMENTAL IMPORTANCIA EN ELECTRONICA Y FOTONICA. TAMBIEN PRETENDEMOS SINTETIZAR DIVERSOS COMPUESTOS FUNCIONALES DE GRAN INTERES EN MAGNETISMO Y ESPINTRONICA (COMO LOS LLAMADOS "SINGLE-MOLECULE MAGNETS", "SINGLE-CHAIN MAGNETS", POLIMEROS CONDUCTORES, COMPUESTOS CON TRANSICION DE ESPIN, ETC. FINALMENTE, QUIZAS CON UNA APLICACION PRACTICA MAS INMEDIATA, SE SINTETIZARAN "NANOCLUSTERS" Y "NANOPARTICULAS" DE TAMAÑO, FORMA Y REACTIVIDAD CONTROLADA EN EL INTERIOR DE ESTOS MOFS. RESULTADOS ALTAMENTE EXCITANTES Y PROMETEDORES DE TODOS ESTOS COMPUESTOS HAN SIDO YA OBTENIDOS (VER SECCION C)._x000D_ FINALMENTE, ESTE PROYECTO, QUE PLANTEA LA SINTESIS DE NUEVOS MATERIALES CON POSIBLES APLICACIONES REALES EN CATALISIS, ELECTRONICA O ESPINTRONICA, POR EJEMPLO, SE ENMARCA PERFECTAMENTE DENTRO DE LOS OBJETIVOS PLANTEADOS EN HORIZON 2020. (Spanish)
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THIS PROPOSAL AIMS TO TAKE A STEP FURTHER IN THE USE OF A TYPE OF POROUS MATERIALS, CALLED METAL-ORGANIC FRAMEWORKS (MOFS), AS NANO-REACTORS FOR THE DESIGN OF NEW ADVANCED MATERIALS WITH TECHNOLOGICAL APPLICATIONS AS WELL AS FOR THE STUDY OF BIOLOGICAL PROCESSES OF FUNDAMENTAL INTEREST IN LIFE SCIENCES. TO THIS END, WE HAVE DESIGNED A NOVEL SYNTHETIC STRATEGY CONSISTING OF A PRIOR RATIONAL DESIGN OF MOFS WITH FUNCTIONAL CHANNELS (IN SIZE, SHAPE AND REACTIVITY) AND THE SUBSEQUENT APPLICATION OF THE SO-CALLED POST-SYNTHETIC METHODS. From this mode, NEW FUNCIONAL SPECIES will be synthesised, by means of a process of MOLECULAR recognition, IN THE INTERIOR OF THE PORES OF MOFS, THIS FISH AND CHIMICAL PROPERTYS WITH THE PROPERTY OF POROS DICHS._x000D_ THE USE OF MOFS, as “CHIMICAL REACTORS” has recently emerged as one of the most promising visions for the design of financial new materials. However, this STRATEGY STRATEGY SUBMITTED SERVICE FROM THE CONTROL OF THE FINAL SPECIE STRUCTURE, YOUR STRUCTURAL CHARACTERISATION AND THE CONTROL OF THE OWNERS OF THE RESULTING SPECIES._x000D_ The present project is located in the centre of the diminished defices. THEREFORE, WITH THE PROMISING PERSPECTIVE OF OUR PRELIMINARY RESULTS (SEE SECTION C), OUR STRATEGY IS BASED ON A PREVIOUS DESIGN OF A LONG BATTERY OF MOFS OF CONTROLLED POROSITIES IN TERMS OF SIZE, SHAPE AND FUNCTIONALITY. NEXT, NEW FUNCTIONAL SPECIES WILL BE CHEMICALLY SYNTHESISED INSIDE THESE APROVECHANDON PORES OF THE TEMPLATE EFFECT OF THEM AS WELL AS THEIR PROPERTIES. In addition, we intend to use CHRISTALOGRAPHY as a powerful tool to carry light on the structuring of the created species, and I have a step beyond all that I have done._x000D_ Have in mind all things improved, new MATERIALS ADVANCED WITH DIVERSAS AND NEW CHIMICAL PROPIEDS (CATALISIS, biomimetics, ETC) and PHYSICAS (OPTICAS, ELECTRICAS, MAGNETICAS, Drivers, ETC) will be synthesised. THESE NEW MATERIALS ARE INTENDED TO HAVE APPLICATION IN THE FIELD OF MULTIFERROICS (AND NONLINEAR OPTIC MATERIALS), WHICH ARE OF FUNDAMENTAL IMPORTANCE IN ELECTRONICA AND FOTONICA. WE ALSO INTEND TO SYNTHESISE VARIOUS FUNCTIONAL COMPOUNDS OF GREAT INTEREST IN MAGNETISM AND SPINTRONICA (SUCH AS THE SO-CALLED “SINGLE-MOLECULE MAGNETS”, “SINGLE-CHAIN MAGNETS”, CONDUCTIVE POLYMERS, COMPOUNDS WITH ESPIN TRANSITION, ETC.. FINALLY, PERHAPS WITH A MORE IMMEDIATE PRACTICAL APPLICATION, “NANOCLUSTERS” AND “NANOPARTICULAS” OF SIZE, FORM AND CONTROLLED REACTIVITY WITHIN THESE MOFS WILL BE SYNTHESISED. High EXCITANT RESULTS AND PROMETTORS OF ALL THESE COMPOSES HAVE BEEN AND OBTENTED (see SECTION C)._x000D_ FINALENT, this project, which PLANTS THE SINTESIS OF NEW MATERIALS WITH POSSIBLE REAL APPLICATIONS IN CATALISIS, ELECTRONICAL OR SPINTRONICAL, FOR exemplar, is framed PERFECTLY DENTRE OF OBJECTIVES PLANTEED IN HORIZON 2020. (English)
12 October 2021
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Paterna
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Identifiers
CTQ2016-75671-P
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